Scott R. Daly

Professor
Biography

Keywords

  • Inorganic and organometallic chemistry
  • Coordination chemistry
  • Ligand synthesis and design
  • X-ray absorption spectroscopy

Research interests

The Daly Group uses coordination chemistry to address fundamental questions relevant to nuclear energy and materials, small molecule transformations, separations, and electroactive molecules. While the applications are quite diverse, our projects are similar in that they rely on the design of new ligands capable of promoting a desired function or property when bound to metals. Students in the group learn to characterize new complexes using a wide range of physical and analytical methods that include multi-nuclear NMR spectroscopy, single-crystal X-ray diffraction, mass spectrometry, X-ray absorption spectroscopy, and electrochemical methods. Our efforts generally fall into one of the following research areas: development of transition metal complexes with redox-active and dinucleating ligands, X-ray spectroscopy investigations of metal complexes with boron and phosphorus ligands, and the synthesis of lanthanide and actinide borohydride complexes. Please see our website for additional details.

Recent publications 

  • Ananda Nakath Durage, J. L.; Cardona, C.; Sinhababu, S.; Duffy, D. H.; Martinez, D.; Shores, M. P.; Unruh, D. K.; Vlaisavljevich, B.; Daly, S. R. "Leveraging Chelating Amido Ligands to Support Metal-Metal Bonding in Dinuclear Cr(II) Complexes." Inorg. Chem. 2026, 65, 5850-5863.
  • Hansen, H. M.; Zgrabik, J. C.; Zacher III, P. A.; Schuely, J. J.; Amano, E. M.; Yang, M. Y.; Unruh, D. K.; Zuin, L.; Keith, J. M.; Daly, S. R. "Direct Measurement of Covalent Three-Center, Two-Electron M-H-B Bonding in Zr and Hf Borohydrides using B K-edge XAS." Chem. Sci. 2025, 16, 22333–22347.
  • Luna, J. A.; Spielvogel, K. D.; Loutsch, N. R.; Loria, S. M.; Weisburn, L. P.; Ringenberg, M. R.; Vlaisavljevich, B.; Keith, J. M.; Shaw, S. K.; Daly, S. R. "Spectroscopic and Theoretical Studies of Ruthenium Complexes with a Noninnocent N2S2 Ligand in Different Redox States." Inorg. Chem. 2025, 64, 15961–15979.
  • Hansen, H. M.; Garg, P.; Schuely, J. J.; Yang, M. Y.; Farha, O. K.; Keith, J. M.; Daly, S. R. "Flash Communication: Boron K-edge XAS and TDDFT Studies of Covalent Metal-Ligand Bonding in Ni(C2B9H11)2." Organometallics 2025, 44, 1624–1629.
  • Zacher III, P. A.; Unruh, D. K.; Daly, S. R. "Synthesis of Bulky Hydride Ligands: m-Terphenylborohydride Complexes with Trivalent Uranium and Neodymium." Dalton Trans. 2025, 54, 9135–9139.
  • Zgrabik, J. C.; Lussier, D. J.; Bhowmick, R.; Nguyen, N.; Zacher III, P. A.; Elkin, T.; Gaunt, A. J.; Goff, G. S.; Mason, H. E.; Murillo, J.; Scott, B. L.; Vlaisavljevich, B.; Daly, S. R. "Structural and Theoretical Assessment of Covalency in a Pu(III) Borohydride Complex." J. Am. Chem. Soc. 2024, 146, 25943–25948.
  • Spielvogel, K. D.; Campbell, E. J.; Chowdhury, S. R.; Benner, F.; Demir, S.; Hatzis, G. P.; Petras, H. R.; Sembukuttiarachchige, D.; Shepherd, J. J.; Thomas, C. M; Vlaisavljevich, B.; Daly, S. R. "Modulation of Fe-Fe Distance and Spin in Diiron Complexes Using Tetradentate Ligands with Different Flanking Donors." Chem. Commun. 2024, 60, 8399-8402.
  • Zgrabik, J. C.; Bhuniya, B.; Branstad Phillips, T.; Barroso, J.; Vlaisavljevich, B.; Daly, S. R. "Volatile Lanthanide Complexes with Fluorinated Heptadentate Ligands." Dalton Trans. 2024, 53, 2998-3009.
  • Zgrabik, J. C.; Bhowmick, R.; Eckstrom, F. D.; Harrison, R. A.; Fetrow, T. V.; Blake, A. V.; Vlaisavljevich, B.; Daly, S. R. "Comparative Study of Alkyl Substituent and Metal Size on the Structures of Trivalent f-Element Phosphinodiboranates." Inorg. Chem. 2024, 63, 9451-9463.
Research areas
  • Inorganic chemistry
  • Radiochemistry
Scott Daly
Phone
Education
Seaborg Postdoctoral Fellow, Los Alamos National Lab
PhD, University of Illinois at Urbana-Champaign
BS, North Central College
Contact Information
Address

University of Iowa
W474 Chemistry Building (CB)
230 N. Madison Street
Iowa City, IA 52242
United States